Iron oxide recovery from fayalite
Abstract
Fayalite (Fe2SiO4) as the main composition of copper slag contains abundant Fe2+. Reasonable application of fayalite is of great interest for comprehensive use of mineral resource and reduction of environmental problems. In this work, the oxidation behavior of fayalite in water vapor was investigated. Fayalite was decomposed into magnetite (58.8 wt%), hematite (21.6 wt%) and silica (19.6 wt%) at 1000 °C for 40 min under water vapor condition. Compared with the result obtained in dry air, water vapor could promote fayalite to transform into magnetite by decreasing oxygen fugacity. In addition, the iron oxide product was further enriched via alkaline cleaning in 1 mol/L NaOH. As for the gas product, the hydrogen production capacity reached 24.41 mL/g when exposed to 50 vol% water-50 vol% Ar at 1000°C for 40 min.
References
(1) Name: Zuotai Zhang
Acedamic dgree: Doctor
Institution: Peking Univerisity, China
Email address: zuotaizhang@pku.edu.cn
Expert in this field
(2) Name: Klaus G. Nickel,
Acedamic dgree: Doctor
Institution: Universität Tübingen, Germany,
Email address: klaus.nickel@uni-tuebingen.de
Expert in this field
(3)Name: Zhaohui Huang
Acedamic dgree: Doctor
Institution:China University of Geosciences(Beijing),China
Email address: huang118@cugb.edu.cn
Expert in this field
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