Thermodynamic modeling of the Hf-N system

  • Mengde Pang State Key Lab of Powder Metallurgy, Central South University
  • Yingbiao Peng College of Metallurgy and Material Engineering, Hunan University of Technology
  • Peng Zhou School of Mechanical and Electrical Engineering, Hunan University of Science and Technology
  • Yong Du State Key Lab of Powder Metallurgy, Central South University

Abstract


Hf-N based alloys have been widely used and studied in the fields of electronic devices and cutting tools industry. A thermodynamic description of this system is essential for further development of these alloys. By means of CALPHAD method, thermodynamic modeling of the Hf-N system was carried out based on the available phase diagram data as well as thermodynamic property data. The Fcc phase is modeled as (Hf, Va)1(N, Va)1 to cover the composition range since the solubility of nitrogen in Fcc phase is reported up to about 52 at.%. A set of self-consistent thermodynamic parameters for the Hf-N system has been obtained. The computed phase diagrams and thermodynamic quantities using the present parameters agree well with the experimental data.

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Published
2017/12/29
How to Cite
Pang, M., Peng, Y., Zhou, P., & Du, Y. (2017). Thermodynamic modeling of the Hf-N system. Journal of Mining and Metallurgy, Section B: Metallurgy, 54(1), 111-118. Retrieved from https://aseestant.ceon.rs/index.php/jmm/article/view/14086
Issue
Vol. 54 No. 1 (2018)
Section
Original Scientific Paper

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