Thermodynamic Modelling of the Lead Sintering Roasting Process
Abstract
This work proposes a simulation strategy of the lead sintering process assuming that it takes place in a horizontally moving packed bed with transverse air flow. Some local chemical reactions occur at rates depending on the temperature; chemical species formed in one volume stage will flow for further reaction in other stages. To simulate this process, the model reactor is divided into a number of sequential stages. Condensed species flow horizontally and gaseous species leave each stage vertically. The compositions and temperatures of the species are calculated considering that the local thermodynamic equilibrium is reached in each stage without external heat transfer, apart from the gas flow, before moving on to the next stage. The model calculates the temperature profile along the sintering machine, the compositions of the sinter and the exhaust gas. The results of the proposed model are compared with sinter pot experimental trials and a reasonably good agreement was obtained. This model can be used to optimize the operating conditions of the lead sintering process.
References
F. Habashi, Handbook of Extractive Metallurgy. Primary metals, secondary metals, light metals. New York, Wiley-VCH, 1997.
R. Sinclair, The Extractive Metallurgy of Lead. Carlton Victoria, Australia. The Australian Institute of Mining and Metallurgy, 2009.
J. P. Bellot, F. Patisson and D. Ablitzer, Metallurgical Transactions B, 24B (1993) 27-38.
J. R. Siemon, E. Kowalczyk, D. P. Fitzgibbons and W. Baguley, Minerals Engineering, 4 (1991) 63-78.
C. Xu, M. Wu and J. She, Proc. 6th World Congress on Intelligent Control and Automation, Dalian, China. 2006, p. 1861-1865.
W-H. Gui, C. H. Yang and J. Teng, International Journal of Automation and Computing, 4 (2) (2007) 135-140. DOI: 10.1007/s11633-007-0135-z.
H. Zhou, J. P. Zhao, C. E. Loo, B. G. Ellis and K. F. Cen, ISIJ Int., 52 (9) (2012) 1550-1558. DOI: http://dx.doi.org/10.2355/isijinternational.52.1550.
J. Saiz, M. A. Posada, ISIJ Int., 53 (2013) 1658-1664. DOI: http://dx.doi.org/10.2355/isijinternational.53.1658
I. Barin, Thermochemical Data of Pure Substances. Berlin, Wiley, 1989.
Y. Lwin, Int. J. Eng. Ed., 16 (4) (2000), 335-339.
W. R. Smith and R. W. Missen, Chemical Reaction Equilibrium Analysis: Theory and Algorithms. John Wiley and Sons. New York, 1982.
G. Eriksson and E. Rosen, Chemica Scripta, 4 (1973) 193-194.
C. E. Loo and R. D. Dukino, Miner. Process. Extr. Metall., 123 (4) (2014) 191-196. DOI 10.1179/1743285514Y.0000000064.
C. E. Loo and R. D. Dukino, Miner. Process. Extr. Metall., 123 (4) (2014) 197-203. DOI 10.1179/1743285514Y.0000000065.
B. Zhao, Sintering Applications. Chapter 8 Lead and Zinc Sintering. http://dx.doi.org/10.5772/56064. Edited by Burcu Ertu, 2013, p. 165-200.
- Figure 1. Schematic representation of the sinter machine.
- Figure 2. Reactor structure for the modeling of the sinter machine.
- Figure 3. Illustration of the steps to estimate the equilibrium temperature in each stage.
- Figure 4. Example of the species reacting at a given stage (mass in kg).
- Figure 5. Measured and calculated temperature in the sinter pot trial.
- Figure 6. Bed temperature profiles against distance, obtained with pellet A.
- Figure 7. Bed temperature profiles against distance, obtained with pellet B.
- Figure 8. Predicted SO2 content in the exhaust gas against distance, obtained with pellets A and B.
Authors retain copyright of the published papers and grant to the publisher the non-exclusive right to publish the article, to be cited as its original publisher in case of reuse, and to distribute it in all forms and media.
The Author(s) warrant that their manuscript is their original work that has not been published before; that it is not under consideration for publication elsewhere; and that its publication has been approved by all co-authors, if any, as well as tacitly or explicitly by the responsible authorities at the institution where the work was carried out. The Author(s) affirm that the article contains no unfounded or unlawful statements and does not violate the rights of others. The author(s) also affirm that they hold no conflict of interest that may affect the integrity of the Manuscript and the validity of the findings presented in it. The Corresponding author, as the signing author, warrants that he/she has full power to make this grant on behalf of the Author(s). Any software contained in the Supplemental Materials is free from viruses, contaminants or worms.The published articles will be distributed under the Creative Commons Attribution ShareAlike 4.0 International license (CC BY-SA).
Authors are permitted to deposit publisher's version (PDF) of their work in an institutional repository, subject-based repository, author's personal website (including social networking sites, such as ResearchGate, Academia.edu, etc.), and/or departmental website at any time after publication.
Upon receiving the proofs, the Author(s) agree to promptly check the proofs carefully, correct any typographical errors, and authorize the publication of the corrected proofs.
The Corresponding author agrees to inform his/her co-authors, of any of the above terms.