Selective leaching of Mo from off-grade gravity lead concentrate in Na2CO3 solution
Abstract
A green process was developed to treat an off-grade gravity lead concentrate. The selective leaching of Mo from an off-grade gravity lead concentrate was investigated in Na2CO3 solution using air as an oxidant. The leaching behaviors of Mo and Pb were predicted by the thermodynamic phase diagrams of Pb-Mo-C-H2O system. The oxidation mechanisms of those sulfides in the off-grade gravity lead concentrate were confirmed by these methods of X-ray diffraction (XRD) and scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS). The influence of operating factors on the leaching behaviors of Mo and Pb was studied including Na2CO3 concentration, liquid-to-solid ratio, temperature and leaching time. Under these optimum leaching conditions (Na2CO3 2 mol/L, leaching time 8 h, temperature 75 °C, air-flow rate 2.0 m3/h and L/S ratio of 10/1 mL/g), the extraction of Mo and Pb was up to 97.70 and 0.73 percent, respectively.
References
P. Xian, S. Zhou , M. Wang, X. Wang, B. Chen, Trans. Nonferrous Met. Soc. China, 27(1) (2017), 220–226.
Y. Zhao, C. Zhang, Springer International Publishing AG, Switzerland, (2017).
M. Wang, C. Wei, G. Fan, Z. Deng, S. Wang, J. Wu, Rare Met, 32(2) (2013) 208–212.
T. Smolinski, D. Wawszczak, A. Deptula, L. Wieslawa, T. Olczak, M. Rogowski, M. Pyszynska, A.G. Chmielewski, J. Radioanal Nucl. Chem., 314(1) (2017) 69–75.
Z. Liu, Y. Xiang, J. Jiang , Y. Chen , L. Xiong, Trans. Nonferrous Met. Soc. China, 26(2) (2016) 565−574.
J. Liang, H. Liu, W. Shi, E. Hu, Journal of University of South China (Science and Technology), 31(2) (2017) 20–24 (in Chinese).
H. Wang, Y. Xiao, M. Wang, K. Xie, Nonferrous Metals Engineering, 5(2) (2015) 39–43 (in Chinese).
Y. Liu, Y. Zhang, F. Chen, Y. Zhang, Hydrometallurgy, 129 (2012) 30–34.
F. Li, W. Zhang, L. He, Z. Zhao, Int. Journal of Refractory Metals and Hard Materials, 62 (2017) 14–20.
A. Khoshnevisan, H. Yoozbashizadeh, M. Mozammel, S. Sadrnezhaad, Hydrometallurgy, 111–112 (2012): 52–57.
K. Jiang, Y. Wang, X. Zou, L. Zhang, S. Liu, JOM, 64 (11) (2012) 1285–1289.
S. Joo, Y. Kim, J. Kang, H. Yoon, D. Kim, S. Shin, Mater. Trans., 53 (11) (2012) 2038– 2042.
W. Zhang, J. Li , Z. Zhao, S. Huang , X. Chen, K. Hu,. Hydrometallurgy, 155 (2015) 1–5.
S. Yang, Y. Cao, H. Liu, Z. Gao, Nonferrous metals (smelting section), 5 (2011) 31–33 (in Chinese).
H. Abdollahi, M. Noaparast, S. Z. Shafaei, Z. Manafi, J.A. Muñoz, O. H. Tuovinen.. International Biodeterioration & Biodegradation, 104 (2015) 194–200.
H. Abdollahi, S.Z Shafaei, M. Noaparast, Z. Manafi, N. Aalan. Trans. Nonferrous Met. Soc. China, 23(1) (2013) 219–230.
Y. Liu, H. Zhong , Z. Cao, Mining Science and Technology, 21(1) (2011) 61–64.
K.H. Park, D. Mohapatra, B.R. Reddya Journal of Hazardous Materials B, 138(2006) 311–316.
Z. Zhao, G. Zhang, G. Huo, H. Li, Hydrometallurgy, 97(3-4) (2009) 233–236.
S.A. Williams, Economic Geology, 58 (1963)1119–1125.
J. Wen, A. Wang, F. Xia, D. Xu, T. Yang, J. Sustain. Metall., 3(3) (2018) 429–440.
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