3D computer model of the Co-Cu-CoS-Cu2S subsystem T-x-y diagram above 800oC
Abstract
The three-dimensional computer model of the Co-Cu-CoS-Cu2S subsystem T-x-y diagram at temperatures above 800oC is represented. It is shown that the liquid immiscibility in the binary subsystem Cu-Cu2S is transformed within the ternary system with Co into the wide two-phase region of two immiscible melts, which interrupts the univariant curve of the Co and Cu2S co-crystallization. The special features of the structure of the solidus surface of cobalt, caused by liquid-phase immiscibility are considered.
References
F. Kongoli, Y. Dessureault, A. D. Pelton, Metall. Mater. Trans. B, 29(3) (1998) 591-601, https://link.springer.com/journal/11663/29/3.
W. Viljoen, Phase Relations in the System Cu-Fe-Ni-S and their Application to the Slow Cooling of PGE Matte, University of Pretoria, Pretoria, 2001, p. 139,
V. Raghavan, J. Phase Equilib., 25(5) (2004) 458-461, doi: 10.1361/15477020421188.
V. I. Kosyakov, E. F. Sinyakova, Inorg. Mater., 48(7) (2012) 671-675, doi: 10.1134/S0020168512060076.
V. I. Kosyakov, E. F. Sinyakova, Inorg. Mater., 47(6) (2011) 660-664, doi: 10.1134/S002016851105013X.
R. V. Starykh, S. I. Sineva et al, Russ. Metall., 3 (2009) 263-270, doi: 10.1134/S0036029509030136; 5 (2009) 447-453, doi: 10.1134/S0036029509050164; 5 (2010) 448-455, doi: 10.1134/S0036029510050162; 11 (2010) 1025-1031, doi: 10.1134/S0036029510110066; 3 (2012) 189-194, doi: 10.1134/S0036029512030135.
V. I. Lutsyk, V. P. Vorob’eva, A. E. Zelenaya, Adv. Mater. Letters, 10(1) (2019) 53-57, doi: 10.5185/amlett.2019.2172.
V. I. Lutsyk, V. P. Vorob'eva, Rus. J. Phys. Chem., 91(13) (2017) 2593-2599, doi: 10.1134/S0036024417130131.
W. J. Schlitt, R. H. Craig, K. J. Richards, Metall, Mater. Trans. B, 4(8) (1973) 1994-1996, https://link.springer.com/journal/11663/4/8/page/2.
S. L. Lee, M. J. Larrian, H. H. Kellogg, Metall. Mater. Trans. B, 11(2) (1980) 251-255, https://link.springer.com/journal/11663/11/2.
Y. Y. Chuang, Y. A. Chang, Metall. Mater. Trans. B, 13(3) (1982) 379-385, https://link.springer.com/journal/11663/13/3.
F. Tesfaye, D. K. Lindberg, P. Taskinen, Proceedings of EPD Congress 2016 (The Mineral, Metals & Materials Society), 14-18 February 2016, Nashville, USA, p. 29-37.
A. Sugaki, H. Shima, A. Kitakaze, H. Harada, Econ. Geol., 70(4) (1975) 806-823, doi: https://doi.org/10.2113/gsecongeo.70.4.806.
A. Kitakaze, Mem. Fac. Eng. Yamaguchi Univ., 68(2) (2017) (55)23-(75)44, http://www.msoc.eng.yamaguchi-u.ac.jp/research/pdf/6_3.pdf
V. I. Lutsyk, V. P. Vorob'eva, A. M. Zyryanov, S. Ya. Shodorova, Proceedings of Takano Intl. Symp. Metals & Alloys Processing (SIPS 2015), 4 - 9 October 2015, Antalya, Turkey, 2015, p. 305-326.
J. R. Craig, D. J. Vaughan, J. B. Higgins, Econ. Geol., 74(3) (1979) 657-671, https://doi.org/10.2113/gsecongeo.74.3.657.
M. O. Ilatovskaya, R. V. Starykh, S. I. Sinyova, Metall. Mater. Trans. B, 45(5) (2014) 1757-1768, doi: 10.1007/s11663-014-0096-x.
M. O. Ilatovskaya, R. V. Starykh, Metall. Mater. Trans. B., 46(1) (2015) 243-249, doi: 10.1007/s11663-014-0202-0.
M. O. Ilatovskaya, S. I. Sinyova, R. V. Starykh, CALPHAD, 59 (2017) 31-39, http://dx.doi.org/10.1016/j.calphad.2017.07.007.
J. E. Morral, S.-L. Chen, J. Phase Equilib. Diffus, 38(3) (2017) 319-331, doi: 10.1007/s11669-017-0547-6.
V. I. Lutsyk, V. P. Vorob'eva, Therm. Anal. Calorim., 101(1) (2010) 25-31, doi: 10.1007/s10973-010-0855-0.
Binary Alloy Phase Diagrams. (Editor T. B. Massalski), American Society for Metals, Ohio, 1986, Vol. 1, Vol. 2.
Diagrammy sostoyaniya dvoynykh metallicheskikh system, Vol. 2 (Editor N. P. Lyakishev), Mashinostroyenie, Moscow, 1997; State Diagrams of Binary Metal Systems Vol. 2. (Editor N. P. Lyakishev), Mashinostroyenie, Moscow, 1997 (In Russian).
V. I. Lutsyk, V. P. Vorob'eva, A. E. Zelenaya, Solid State Phenomena, 230 (2015) 51-54, doi: 10.4028/www.scientific.net/SSP.230.51.
V. I. Lutsyk, A. M. Zyryanov, A. E. Zelenaya, Rus. J. Inorgan. Chem., 53(5) (2008) 794-799, doi: 10.1134/S0036023608050203.
V. I. Lutsyk, A. E. Zelenaya, V. P. Vorob’eva, Abstr. Intern. Conf. on Phase Diagram Calculations and Computational Thermochemistry (CALPHAD XXXVIII), 17–22 May 2009, Prague, Czech Rep., 2009, p. 146.
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