RAY DIFFRACTION STADY OF STRUCTURE OF CaO—Al2O3—SiO2 TERNARY COMPOUNDS IN MOLTEN AND CRYSTALLINE STATES

  • Vladimir Sokol'skii Taras Shevchenko National University of Kyiv
  • Dmitriy Pruttskov ZAO «Tekhnokhim», Zaporozhye, Ukraine
  • Oleksiy Yakovenko Taras Shevchenko National University of Kyiv
  • Volodymyr Kazimirov Taras Shevchenko National University of Kyiv
  • Oleksandr Roik Taras Shevchenko National University of Kyiv
  • Natalia Golovataya Taras Shevchenko National University of Kyiv
  • Georgii Sokolsky National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute

Abstract


Anorthite and gelenite crystalline structure and short range order of anorthite melt have been studied by X-ray diffraction in the temperature range from room temperature to ~1650  C. The corresponding anorthite and gelenite phases were identified as well as amorphous component for anorthite samples having identical shape to XRD pattern of the anorthite melt. The structure factor and the radial distribution function of atoms of the anorthite melt were calculated from the X-ray high-temperature experimental data. The partial structural parameters of the short-range order of the melt were reconstructed using Reverse Monte Carlo simulations.

References

V. Sokol’skii, A. Roik, A. Davidenko, V. Kazimirov, V. Lisniak, V. Galinich, I. Goncharov, J. Min. Metall. Sect. B-Metall., 48 (1) B (2012) 101-113. doi:10.2298/JMMB101223002S.

E. Pastukhov,N. Vatolin, V. Lisin. et al. Diffraction studies of a structure of high-temperature melts. Ur. Div. Rus. Acad. Sci. Ekaterinburg: 2003. p.544.

N.Vatolin, E. Kern, V.Lisin, X-Ray diffraction study of the structure of the silicate melts. Chapter I in Structure and physical-chemical properties of metallic and oxide melts. UNC AN USSR. Sverglovsk, 1986, p.38-56.

E. Kern, I. Cherniavsky, L. Ziatkova, N. Vatolin, Glass Physics and Chemistry, 14 (1988) 2 182-186.

E. Kern, I. Cherniavsky, L.Ziatkova, N.Vatolin. Glass Physics and Chemistry, 12 (1988) 2 206-212.

V.E. Sokol’skii, D.V. Pruttskov , V.M. Busko, V.P. Kazimirov, O.S. Roik , A.D. Chyrkin , V.I. Galinich, I.A. Goncharov, J. Min. Metall. 54 (2) B (2018) 133 – 141. doi:10.2298/JMMB170908001S.

D.V. Pruttskov, V.E. Sokol’skii, E.V. Alekseev, V.P. Kazimirov, A.S. Roik, E.A. Vovchenko, Refractories and technical ceramics, 7-8 (2018) 3-12.

A.S. Berezhnoi, Multicomponent alkali oxide systems, Naukova dumka, Kiev, 1970, p. 458.

V. Sokol’skii, O. Roik, V. Kazimirov, Practical Application of X-Ray Analysis to the study of Welding Fluxes in Hight Temperature, Chapter 5 in Advances in Materials Science Research V20: Nova Science Publishers, NY, 2015. p. 95-128.

V. Sokol’skii, V. Kazimirov, O. Roik and al., Welding Fluxes: Structural and physicochemical aspects of slag melts. PPC “The University of Kyiv”, Kiev, 2015. p. 240

R.L. McGreevy, RMC techniques for structural modeling, Computer Modelling in Inorganic Crystallography, ed. C.R.A. Catlow. – London: Academic Press, 1997. – P.151 – 184. doi: 10.1016/B978-012164135-1/50007-1.

A Le Ball, J. Non-Cryst. Solids, 271 (2000) 3 249–259. doi: 10.1016/S0022-3093(00)00106-X.

D.A. Keen, R.L. McGreevy, Nature, 344(1990) 423–4. doi: 10.1038/344423a0.

A. Ilinskii, A. Romanova, L. Mikchailova and al., Metallofizica. 13 (1991) 2 119-122.

] J.R. Johnson, R.W. Bristow and H.H. Blau, J. Amer. Ceramic Soc. 34 (1951) 6 165-172. doi:10.1111/j.1151-2916.1951.tb11630.x.

J. H. Welch, W. Gutt, J. Amer. Ceramic Soc. 42(1959) 1 11-15. doi: 10.1111/j.1151-2916.1959.tb09135.x.

Published
2020/09/15
How to Cite
Sokol’skii, V., Pruttskov, D., Yakovenko, O., Kazimirov, V., Roik, O., Golovataya, N., & Sokolsky, G. (2020). RAY DIFFRACTION STADY OF STRUCTURE OF CaO—Al2O3—SiO2 TERNARY COMPOUNDS IN MOLTEN AND CRYSTALLINE STATES. Journal of Mining and Metallurgy, Section B: Metallurgy, 56(2), 269-277. Retrieved from https://aseestant.ceon.rs/index.php/jmm/article/view/23190
Section
Original Scientific Paper