Insight on the reduction of copper content in slags produced from the Ausmelt Converting Process

  • Haibin Yuan 1. Kunming University of Science and Technology, Kunming 2. Copper Branch of Yunnan Tin Company Limited
  • Bin Cai Kunming university of science and technology
  • Xing-cheng SONG Copper Branch of Yunnan Tin Company Limited
  • Du-zuo TANG Copper Branch of Yunnan Tin Company Limited
  • Bin Yang 1. Kunming University of Science and Technology
Keywords: Top-blown converting; Copper content in slag; Copper matte; Blister copper; Reduction; Ausmelt Furnace

Abstract


The reduction of copper content in converting slag by using process control technology is significant to copper smelter. In this study, the slags produced from the Ausmelt Converting Process for copper matte have been analyzed by X-ray diffraction and chemical analysis. Theoretical calculation and effects of various conditions including lance submerging depth in molten bath, molten bath temperature, the addition of copper matte, and air flow rate were carried out to lower the content in the copper. Theoretical analysis indicates that the decrease of copper content in the slag by reducing Fe3O4, CuFe2O4 and Cu2O in the slag, decreasing the magnetism level of slag and improving the viscosity of slag is feasible at the operating temperature of the molten bath. Experimental results show that the copper content in the slag can be effectively reduced from 22.74 wt. % to 7.70 wt. %. This study would provide a theoretical support and technical guidance for promoting the utilization of mineral resources.

References

[1] M.D. Turan. Optimization of selective copper extraction from chalcopyrite concentrate in presence of ammonium persulfate and ammonium hydroxide, Int J. Miner. Process., 26(2019): 946-952.
[2] J.M. Floyd. Converting an idea into a worldwide business commercializing smelting technology, Metallurgical and Materials Transactions B, 36B(2005): 557-575.
[3] The editorial board of Heavy non-ferrous metal smelting Design Handbook. Handbook of heavy non-ferrous metal smelting (copper nickel). 1996 Beijing: Metallurgy industry Press,. (In Chinese)
[4] Jun Zhang, Yuan-hong Qi, Ding-liu Yan, Xiang-li Cheng, Peng He. Characteristics and mechanism of reduction and smelting-separation process of copper slag, Journal of iron and steel research, International, 22(2015): 121-127.
[5] Afshin Akbari, Esmaeil Rahimi. Effect of copper slag recovery on hydrometallurgical cut-off grades considering environmental aspects, Journal of Central South University, 23(2016): 798-807.
[6] Zhou Ping, Yao Yingjin, Ai Yuanfang, Liu Anming, Xu Zelin, Xie Jiancai. Grey correlation analysis of factors influencing maldistribution in feeding device of copper flash smelting, Journal of Central South University, 19: 1938-1945. (2012)
[7] Gui Weihua, Wang Lingyun, Yang Chunhua, Xie Yongfang, Peng Xiaobo. Intelligent prediction model of matte grade in copper flash smelting process, Transactions of Nonferrous Metals Society of China, 17(2017): 1075-1081.
[8] Peng Cui, Zhu Guocai, Chi Ru-an, Zou Yongqian, Zhao yu-na. Recovery of copper from leaching solution of copper smelting ash, The Chinese Journal of Process Engineering, 7(2007): 273-277.
[9] Chen Chunlin, Zhang Jiayun, Zhou Tuping, Wei Shoukun, Lu Xingxiang, Bai Meng, Jiang Jinhong. Thermodynamic study on process in copper converters (the copper-making stage), Journal of University of Science and Technology Beijing, 7(2000): 184-188.
[10] Wang Qinmeng, Guo Xueyi, Liao Lile, Tian Qinghua, Zhang Yongzhu. Mapping relationship between multicomponent matte formating behavior and content in copper oxygen bottom blowing bath smelting process, The Chinese Journal of Nonferrous Metals, 26(2016): 188-196. (In Chinese)
[11] Wang Qinmeng, Guo Xueyi, Tian Qinghua, Liao Lile, Zhang Yongzhu. Multicomponent slagging behavior and constitution optimization of slag in copper oxygen bottom blowing bath smelting process, The Chinese Journal of Nonferrous Metals, 25(2015): 1678-1686. (In Chinese)
[12] Shui Liang, Cui Zhixiang, Ma Xiaodong, Rhamdhani Ma, Nguyen A V, Zhao Baojun. Mixing phenomena in a bottom blown copper smelter: A water model study, Metallurgical and Materials Transactions B, 46(2016): 1218-1225.
[13] Liu Liu, Yan Hongjie, Zhou Jiemin, Gao Qiang, Zhang Zhenyang, Liu Fangkan, Cui Zhixiang. Mechanism of copper smelting process by oxygen bottom blowing and microanalysis of smelting products, The Chinese Journal of Nonferrous Metals, 22(2012): 2116-2124. (In Chinese)
[14] Mackey P J. The physical chemistry of copper smelting slags: A review,Canadian Metallurgical Quarterly, 21(1982): 221-260.
[15] Sridhar R, Toguri J M, Simeonov S. Copper losses and thermodynamic considerations in copper smelting, Metallurgical and Materials Transactions B, 28(1997): 191-200.
[16] Gao Feng, Shen Qianghua, Wang Chong, Liu Zhonghua, Liu Dafang, Xie Daoqing, Chen Wen, Zhu Weizhong, Zhang Bangqi, Wang Shiming, Lv Wenshuai, Dai Hongkun, Jiang Hong, Tian Shilong, He Yunlong. A device for copper converting slag reduction and dilution. China: CN202226899U [P], 2012.
[17] Gao Feng, Shen Qianghua, Wang Chong, Liu Zhonghua, Liu Dafang, Xie Daoqing, Chen Wen, Zhu Weizhong, Zhang Bangqi, Wang Shiming, Lv Wenshuai, Dai Hongkun, Jiang Hong, Tian Shilong, He Yunlong. A method and apparatus for reducing copper converting slag dilution. China: CN102304623A [P], 2012.
[18] Zhou Shiwei, Wei Yonggang, Zhang Shuoyao, Li Bo, Wang Hua, Yang Yingdong, Bariti Mansoor. Reduction of copper smelting slag using waste cooking oil, Journal of Cleaner Production, 236(2019), 117668.
[19] Li Bo, Wang Xubin, Wang Hua, Wei Yonggang, Hu Jianhang. Smelting reduction and kinetics analysis of magnetic iron in copper slag using waste cooking oil, Scientific Reports, 2406(2017): 1-10.
[20] Jan W. Matousek. Oxidation potential in matte smelting of copper and nickel, JOM, 66(2014): 1670-1676.
[21] Guo Zhengqi, Pan Jian, Zhu Deqing, Yang Congcong. Mechanism of composite additive in promoting reduction of copper slag to produce direct reduction iron for weathering resistant steel, Powder Technology, 329(2018): 55-64.
[22] Olper M, Maccagni M, Matusewicz, R, Ruuter M A. Simplified copper production from primary concentrates: the direct electrorefining metal/copper matte, Canadian Metallurgical Quarterly, 47(2018): 369-376.
Published
2021/09/03
How to Cite
Yuan, H., Cai, B., SONG, X.- cheng, TANG, D.- zuo, & Yang, B. (2021). Insight on the reduction of copper content in slags produced from the Ausmelt Converting Process. Journal of Mining and Metallurgy, Section B: Metallurgy, 57(2), 155-162. Retrieved from https://aseestant.ceon.rs/index.php/jmm/article/view/28875
Section
Original Scientific Paper