Gibbs free energy of formation of Cu2In2O5 ternary phase determined by E.M.F. method

  • Dominika Jendrzejczyk-Handzlik AGH University of Science and Technology, Faculty of Non-Ferrous Metals , Kraków , Poland
  • Piotr Handzlik
Keywords: E.M.F. method, Gibbs free energy, Formation of Cu2In2O5

Abstract


Employing electrochemical cells with the solid zirconia electrolyte:

Cu2O,CuO /O2- / air

Cu2In2O5, In2O3,Cu2O / O2-/ air

In,In2O3 /O2-/ Ni, NiO

Gibbs free energy of formation of solid Cu2In2O5 phase as well as that for In2O3 and CuO oxides was determined in the temperature range from 973 K to 1372 K. The results obtained in this study were used to derive Gibbs free energy change of the reaction of formation of the ternary compound from respective oxides:

2CuO + In2O3 = Cu2In2O5

which is equal to:  (±1400 J/mol). Oxygen potential diagrams for the Cu–In–O system are also given at two temperatures.

 

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Published
2022/12/23
How to Cite
Jendrzejczyk-Handzlik, D., & Handzlik, P. (2022). Gibbs free energy of formation of Cu2In2O5 ternary phase determined by E.M.F. method. Journal of Mining and Metallurgy, Section B: Metallurgy, 58(3), 491-500. Retrieved from https://aseestant.ceon.rs/index.php/jmm/article/view/38642
Issue
Vol. 58 No. 3 (2022)
Section
Original Scientific Paper

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