Corrosion properties of aluminized 16Mo3 steel

  • Blaž Karpe University of Ljubljana,Faculty of Natural Science and Engineering
  • Klara Prijatelj
  • Milan Bizjak
  • Tadeja Kosec
Keywords: aluminide coatings; aluminized steel; aluminizing; electrochemical corrosion investigation; 16Mo3 steel

Abstract


Chromium-molybdenum steel (16Mo3) is widely used in petroleum, gas, automotive, and construction industries due to its good oxidation resistance and mechanical properties at moderately elevated temperatures. The aim of the research was to evaluate the corrosion susceptibility of 16Mo3 steel in hot rolled and aluminized states. Aluminization was performed by diffusion pack aluminization process at 900 °C/2h and 730 °C/4h, respectively. Electrochemical corrosion testing included measuring open circuit potential (EOCP), linear polarization resistance (LPR), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) in potassium phosphate buffer (KH2PO4, pH = 7). Optical microscopy (OM), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS) have been used for surface layer microstructure characterization before and after corrosion tests. It has been demonstrated that corrosion resistance of aluminized steel is increased substantially. Corrosion properties are related to the structure and properties of intermetallic phase (FeAl, FeAl2 and Fe2Al5) formed on the surface of 16Mo3 steel.

References


M. Hofmann, H. Biermann, Static and Cyclic Deformation Behavior of the Ferritic Steel 16Mo3 Under Monotonic and Cyclic Loading at High Temperatures. Steel Research Int. 83 (7), (2012), p. 631-636, https://doi.org/10.1002/srin.201100238

M. Özdemir, H. Hakan Gökmeşe, V. Yilmaz, The development of microstructure and mechanical properties of Cr-Mo high temperature steel in different heat-treated-state. Journal of Basic and Applied Research International 11 (4), (2015) p. 198-205, https://www.ikprress.org/index.php/JOBARI/article/view/3749

J. Metsäjoki, E. Huttunen-Saarivirta, T. Lepistö, Elevated-temperature corrosion of uncoated and aluminized 9–12% Cr boiler steels beneath KCl deposit. Fuel 133, (2014) p. 173-181. https://doi.org/10.1016/j.fuel.2014.05.017

B. Lemmens, Y. Gonzalez Garcia, B. Corlu, J. De Strycke, I. De Graeve, K. Verbeken, Study of the electrochemical behaviour of aluminized steel, Surface and Coatings Technology 26, (2014), p.34-38 https://doi.org/10.1016/j.surfcoat.2014.06.064

M. Akhoondan, A. Sagüés, Corrosion of Aluminized Steel in Aggressive Natural Water. ECS Transactions, The Electrochemical Society 4 (19), (2013), p. 25-35, https://doi.org/10.5006/0879

C. Liang, J. Wei, S. Li, R. Zheng, Electrochemical Behavior of Aluminized Steel in Seawater Environment.  Journal of Electrochemistry 10 (4), (2004), p. 435-439, http://electrochem.xmu.edu.cn/EN/Y2004/V10/I4/435
 
Y. Tamarin, Protective coatings for turbine blades, ASM International, 2002, p. 247

Y. Matsuoka, Y. Matsunaga, K. Nakagawa, Y. Tuda, S. Taniguchi, Growth behaviour of coatings formed by vapour phase aluminizing using Fe-Al pellets of varying composition, The Japan institute of metals, Materials transactions, 47 (9), (2006) p. 2341-2347, https://www.jstage.jst.go.jp/article/matertrans/47/9/47_9_2341/_pdf

Z. Xiang, P. Datta, Effects of pack composition on the formation of aluminide coatings on alloy steels at 650 °C. Journal of Materials Science 40 (8), (2005), p. 1959-1969, https://doi.org/10.1179/026708304225022232

Q. Wang, X. Leng, T. Yang, J. Yan, Effects of Fe-Al intermetallic compounds on interfacial bonding of clad materials, Trans. Nonferrous Met. Soc. China 24, (2014), p. 279-284, https://doi.org/10.1016/S1003-6326(14)63058-2

A. Naji, M.C. Galetz, M. Schutze, Improvements in the thermodynamic and kinetic considerations on the coating design for diffusion coatings formed via pack cementation. Materials and Corrosion, Institute dechema, 66 (9), (2015), p. 863-868, https://doi.org/10.1002/maco.201407810

M. Pourbaix, Atlas of electrochemical equilibria in aqueous solutions. NACE, Huston, (1974)



M.M. Barjesteh, S.M. Abassi, K. Zengeneh Madar, K. Shirvani, Creep Rupture Properties Of Bare And Coated Polycrystalline Nickel-Based Superalloy Rene®80, J. Min. Metall. Sect.B-Metall., 57 (3), (2021), p. 401 – 412, https://doi.org/10.2298/JMMB201203036B

H. Sina, J. Corneliusson, K. Turba, S. Iyengar,  A study on the formation of iron aluminide (FeAl) from elemental powders, Journal of Alloys and Compounds 636, (2015), p. 261-269, https://doi.org/10.1016/j.jallcom.2015.02.132

F. Mansfeld, Fundamental aspects of linear polarization technique-the early days, Journal of Solid State Electrochemistry 13, (2009) p. 515-520, http://dx.doi.org/10.1007/s10008-008-0652-x

A. Berradja, Electrochemical Techniques for Corrosion and Tribocorrosion Monitoring: Methods for the Assessment of Corrosion Rates, IntechOpen, Leuven, (2019), https:/doi: 10.5772/intechopen.85392

S. Papavinasam, Electrochemical polarization techniques for corrosion monitoring: Chapter 3. In: Yang L (ed.) Metals and Surface Engineering, Elsevier, Carson City, (2008), p. 49-85

W. Choi, H. Shin, J.M. Kim, Modelling and Applications of Electrochemical Impedance Spectroscopy (EIS) for Lithium Ion Batteries, Journal of Electrochemical Sci. and Tech.11 (1), (2020), p. 1 13,  https://doi.org/10.33961/jecst.2019.00528

Y. Shi, X.Q. Liu, Z.I. Liu, H.J. Xie, Y.H. Wang, J. Li, Effect of Zn on Corrosion Behaviout of Mg-Y-Zn alloys, J. Min. Metall. Sect B-Metall., 58 (1), (2022), p. 51-61, https://doi.org/10.2298/JMMB210525048S

S. Esmailzade, M. Aliofkhazraei, Interpretation of Cyclic Potentiodynamic Polarization Test Results for Study of Corrosion Behavior of Metals: A Review, Protection of Metals and Physical Chemistry of Surfaces 54, (2016), p. 976-989, https://doi.org/10.1134/S207020511805026X

W. M. Lu, T.J. Pan, Y. Niu, Accelerated corrosion of Fe–xCr–10Al alloys containing 0–20 at% Cr induced by sulphur and chlorine in a reducing atmosphere at 600 °C, Oxid. met. 69, (2008), p. 63–76. https://doi.org/10.1007/S11085-007-9083-9I.

D.V. Lakshmi, P.S. Babu, L.R. Krishna, R. Vijay, D. S. Rao, G. Padmanabham, Corrosion and erosion behaviour of iron aluminide (FeAl(Cr)) coating deposited by detonation spray technique, Advanced Powder Technology, 32, (2021), p. 2192-2201, http://doi.org/10.1016/j.apt.2021.04.032

Y. Alipour, P. Henderson, P. Szakálos, The effect of a nickel alloy coating on the corrosion of furnace wall tubes in a waste wood fired power plant, Materials and Corrosion 65 (2), (2014), p. 217 225, https://doi.org/10.1002/maco.201307118

A. Talus, Y. Alipour, R. Norling, P. Henderson, Effect of sewage sludge addition on initial corrosion of16Mo3 and 310S when exposed in a used wood fired boiler, Materials and Corrosion 67 (7), (2016), p. 683-692: https://doi.org/10.1002/maco.201508693
Standard Practice for Calculation of Corrosion Rates and Related Information from electrochemical Measurements, ASTM G102-89R15E01, USA, DOI:10.1520/G0102-89R15E01

I. Maj, S. Kalisz, A. Szymajda, G. Łaska, K. Gołombek, The influence of cow dung and mixed straw ashes on steel corrosion, Renewable energy, 177, (2021), p. 1198-1211, https://doi.org/10.1016/j.renene.2021.06.019

Published
2023/08/15
How to Cite
Karpe, B., Prijatelj, K., Bizjak, M., & Kosec, T. (2023). Corrosion properties of aluminized 16Mo3 steel. Journal of Mining and Metallurgy, Section B: Metallurgy, 59(1), 91-100. Retrieved from https://aseestant.ceon.rs/index.php/jmm/article/view/40386
Section
Original Scientific Paper