Study of solid state interactions in the systems ZnFe2O4 – CaO, ZnFe2O4 – MgO and zinc cake with CaO and MgO

  • Boyan Boyanov University of Plovdiv, Faculty of Chemistry
  • Alexander Peltekov

Abstract


The solid state interactions of CaO and MgO with synthetic and industrial ZnFe2O4 (in zinc cake) have been studied using chemical, XRD analysis and Mössbauer spectroscopy. The exchange reactions in the systems ZnFe2O4 - CaO and ZnFe2O4 - MgO have been investigated in the range of 850–1200 oC and duration up to 180 min. It has been established that Ca2+ and Mg2+ ions exchange Zn2+ in ferrite partially and the solubility of zinc in a 7% sulfuric acid solution increases. The possibilities for utilization of the obtained results in zinc hydrometallurgy have been discussed.

References

B. S. Boyanov, M. P. Sandalski and K. I. Ivanov, World Academy of Science, Engineering and Technology, 73 (2011) 420-427.

S. Nikolov, B. Boyanov, N. Moldovanska and R. Dimitrov, Thermochimica Acta, 380 (2001) 37-41.

P. Djordjevic, N. Mitevska, I. Mihajlovic, D. Nikolic, D. Manasijevic and Z. Zivkovic, Journal of Mining and Metallurgy, B 48 (2012) 143-151.

S. Katic, I. Ilic and D. Zivkovic, Journal of Mining and Metallurgy, B 45 (2009) 213-220.

A. Blonska-Tabero, M. Bosacka, G. Dabrowska, E. Filipek, M. Piz, I. Rychlowska-Himmel, P. Tabero and E. Tomaszewicz, Journal of Mining and Metallurgy, B 44 (2008) 19-26.

T. T. Chen and J. E. Dutrizac, Journal of Мetallurgy, 56 (2004) 46-51.

J. W. Graydon, and D. W. Kirk, Metallurgical transactions B, Process metallurgy, 19 (1988) 777-785.

S. A. Degterov, E. Jak, P. C. Hayes and A. D. Pelton, Metallurgical and Materials Transactions B, 32 B (2001) 643-657.

H. G. El–Shobaky, Thermochimica Acta, 343 (2000) 145–150.

G. A. El–Shobaky and A. A. Mostafa, Thermochimica Acta, 408 (2003) 75–84.

N. R. E. Radwana, H. G. El-Shobakyb, Thermochimica Acta, 360 (2000) 147-156.

M. R. C. Ismael and J. M. R. Carvalho, Minerals Engineering, 16 (2003) 31–39.

M. Loan, O. M. G. Newman, R. N. G. Cooper, J. B. Farrow and G. M. Parkinson, Hydrometallurgy, 81 (2006) 104-112.

B. S. Boyanov, Journal of Mining and Metallurgy, 41 B (2005) 67-77.

F. Habashi, Journal of Mining and Metallurgy, B 45 (2009) 1-13.

J. E. Clay and G. P. Schoonraad, Journal of the South African Institute of Mining and Metallurgy, 1976, 11-14.

S. I. Evdokimov and A. M. Pan’shin, Russian Journal of Non-Ferrous Metals, 50, 2 (2009) 81-88.

M. R. C. Ismael and J. M. R. Carvalho, Minerals Engineering, 16 (2003) 31–39.

G. Ye and E. Burstrom, Global Symposium on Recycling, Waste Treatment and Clean Technology, Madrid, Spain, September 26 – 29, 2005, 2103-2111.

D. Hirabayashi, T. Yoshikawa, K. Mochizuki , Y. Kojima, K. Suzuki, Y. Sakai, K. Ohshita and Y. Watanabe, Hyperfine Interact, 167 (2006) 809–813.

H. G. El-Shobaky and N. R. E. Radwan, Thermochimica Acta, 398 (2003) 223–231.

A. B. Peltekov and B. Boyanov, University of Plovdiv “Paisii Hilendarski”, Scientific papers, 38, 5 (2011) 177-190.

A. Z. Juhasz, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 141 (1998) 449–462.

V. V. Boldyrev, S. V. Pavlov and E. L. Goldberg, Int. J. Miner. Process, 44-45 (1996) 181-185.

A. M. Gismelseed, K. A. Mohammed, N. M. Widatallah, A. D. Al-Rawas, M. E. Elzain and A. A. Yousif, Journal of Physics: Conference Series, 217 (2010) 012138.

G. A. El-Shobaky, G. A. Fagal, A. Abd El-Aal and A. M. Ghozza, Thermochimica Acta, 256 (1995) 429-411.

B. K. Shahraki, B. Mehrabi, K. Gholizadeh and M. Mahammadinasab, Journal of Mining and Metallurgy, B 47 (2011) 89-97.

P. Lessidrenski, I. Gruev, A. Apostolov, S. Stoyanova and E. Bekrieva, Proceedings of the 4th International Conference ZINC 2006, Plovdiv, Bulgaria, 11-12 September, 2006, 213-216.

A.F.S. Schoukenst, F. Shawt, and E.C. Chemaly, Journal of The South African Institute of Mining and Metallurgy, 93, 1 (1993) 1-7.

S. K. Pardeshi and R. Y. Pawar, Materials Research Bulletin, 45 (2010) 609–615.

G. Ye, E. Burstrom, M. Maccagni, L. Bianco and H. Stripple, Sohn International Symposium; Advanced Processing of Metals and Materials Volume 6: New, Improved and Existing Technologies: Aqueous and Electrochemical Processing, 6 (2006) 397-411.

H. Ehrhardt, S. J. Campbell and M. Hofman, Journal of Alloys and Compounds, 339 (2002) 255.

D. Hirabayashi, T. Yoshikawa, K. Mochizuki , Y. Kojima, K. Suzuki, Y. Sakai, K. Ohshita, and Y. Watanabe, Hyperfine Interact, 167 (2006) 809–813.

T. K. Pathak, N. H. Vasoya, V. K. Lakhani, and K. B. Modi, Ceramics International, 36 (2010) 275–281.

H. Ehrhardt, S.J. Campbell and M. Hofman, Scripta Materialia, 48 (2003) 1141–1146.

Published
2014/02/10
How to Cite
Boyanov, B., & Peltekov, A. (2013). Study of solid state interactions in the systems ZnFe2O4 – CaO, ZnFe2O4 – MgO and zinc cake with CaO and MgO. Journal of Mining and Metallurgy, Section B: Metallurgy, 49(3), 339. Retrieved from https://aseestant.ceon.rs/index.php/jmm/article/view/4081
Issue
Vol. 49 No. 3 (2013)
Section
Original Scientific Paper

Authors retain copyright of the published papers and grant to the publisher the non-exclusive right to publish the article, to be cited as its original publisher in case of reuse, and to distribute it in all forms and media.

The Author(s) warrant that their manuscript is their original work that has not been published before; that it is not under consideration for publication elsewhere; and that its publication has been approved by all co-authors, if any, as well as tacitly or explicitly by the responsible authorities at the institution where the work was carried out. The Author(s) affirm that the article contains no unfounded or unlawful statements and does not violate the rights of others. The author(s) also affirm that they hold no conflict of interest that may affect the integrity of the Manuscript and the validity of the findings presented in it. The Corresponding author, as the signing author, warrants that he/she has full power to make this grant on behalf of the Author(s). Any software contained in the Supplemental Materials is free from viruses, contaminants or worms.

The published articles will be distributed under the Creative Commons Attribution ShareAlike 4.0 International license (CC BY-SA).

Authors are permitted to deposit publisher's version (PDF) of their work in an institutional repository, subject-based repository, author's personal website (including social networking sites, such as ResearchGate, Academia.edu, etc.), and/or departmental website at any time after publication.

Upon receiving the proofs, the Author(s) agree to promptly check the proofs carefully, correct any typographical errors, and authorize the publication of the corrected proofs.

The Corresponding author agrees to inform his/her co-authors, of any of the above terms.