Hydrometallurgical processing of molybdenum middlings from Shatyrkul-Zhaysan cluster ore
Abstract
The results of physical-chemical studies with determination of the material composition of the sample and studies on nitric acid leaching of molybdenum, extraction processing of solutions from molybdenum middlings from the ore of the Shatyrkul-Zhaysan cluster (Republic of Kazakhstan) are presented. Molybdenum intermediate product obtained after the selective flotation of copper-molybdenum concentrate was used in the experiment with a yield of 0.07% with a molybdenum content of 22.23% with an extraction of 74.91%. Studying of ore minerals was carried out in reflected light with the use of a microscope OLYMPUS BX53. During the mineralographic study of the molybdenum intermediate product, an approximate ratio of ore and non-ore minerals was visually established as 80:20%. The process of the intermediate product processing was carried out using one-stage counter-current leaching at atmospheric pressure to reduce the consumption of nitric acid and, consequently, to reduce the residual acidity of the productive solutions, directed to the extraction of valuable components through extraction/re-extraction solutions and precipitation of calcium molybdate. In the process of leaching, the reduction of the residual acidity of the pregnant solution (from 2.3 to 0.89 g-eq/l) due to two-stage leaching allows to considerably increase the extraction/re-extraction stage molybdenum recovery from 58.46% to 94.28%.
Authors retain copyright of the published papers and grant to the publisher the non-exclusive right to publish the article, to be cited as its original publisher in case of reuse, and to distribute it in all forms and media.
The Author(s) warrant that their manuscript is their original work that has not been published before; that it is not under consideration for publication elsewhere; and that its publication has been approved by all co-authors, if any, as well as tacitly or explicitly by the responsible authorities at the institution where the work was carried out. The Author(s) affirm that the article contains no unfounded or unlawful statements and does not violate the rights of others. The author(s) also affirm that they hold no conflict of interest that may affect the integrity of the Manuscript and the validity of the findings presented in it. The Corresponding author, as the signing author, warrants that he/she has full power to make this grant on behalf of the Author(s). Any software contained in the Supplemental Materials is free from viruses, contaminants or worms.The published articles will be distributed under the Creative Commons Attribution ShareAlike 4.0 International license (CC BY-SA).
Authors are permitted to deposit publisher's version (PDF) of their work in an institutional repository, subject-based repository, author's personal website (including social networking sites, such as ResearchGate, Academia.edu, etc.), and/or departmental website at any time after publication.
Upon receiving the proofs, the Author(s) agree to promptly check the proofs carefully, correct any typographical errors, and authorize the publication of the corrected proofs.
The Corresponding author agrees to inform his/her co-authors, of any of the above terms.