Effects of CeO2/Y2O3 rare earth oxides on microstructure and properties of in-situ synthesized WC-reinforced Ni-based cladding layer

  • Cong-xiao Zhang Xi'an University of Science and Technology
  • Wan-chang Sun
  • Er-yong Liu
  • Yu-wan Liu
  • Bo Zhang
  • Meng-ran Zhou
  • Xu Xu
Keywords: Laser cladding, In-situ synthesized, Rare earth, Mechanical properties, Electrochemical properties

Abstract


A novel tungsten carbide (WC)-reinforced nickel (Ni)-based laser cladding layer prepared by in-situ synthesized process. The growth mechanism of the cladding layer was explored. Furthermore, the mechanism of the influence of different concentrations for CeO2/Y2O3 doping on the microstructures, wear and corrosion resistance of in-situ synthesized WC-reinforced Ni-based cladding layer were analyzed. The results revealed that the optimal content of rare earth oxides using the CeO2 content of 0.75% and the Y2O3 content of 1.50%, which exhibit outstanding hardness (660HV0.2) and excellent wear resistance. In addition, the minimum corrosion rate of the coating were 0.002770 mm/a and 0.0022548 mm/a, with the noble Ecorr (-0.12549 V/-0.49924 V) and lower Icorr (2.3550×10-7 A·cm2/1.9170×10-7 A·cm2). The doping of rare earth oxides in the cladding layer excellently enhances the wear and corrosion resistance, which was mainly ascribed to the rare earth oxides have better refining grain and purifying effect on the cladding layer organization.

References

[1]      Huang, Lei, et al. "Microstructure and wear resistance of electromagnetic field assisted multi-layer laser clad Fe901 coating." J. Surf. Coat. Technol., 395.1–8(2020):125876, https://doi.org/10.1016/j.surfcoat.2020.125876


[2]      Li, B. C., et al. "Development of high strength and ductile martensitic stainless steel coatings with Nb addition fabricated by laser cladding - ScienceDirect." J. Alloys Compd., 832(2020), https://doi.org/10.1016/j.jallcom.2020.154985


[3]      Zhai, L. L., C. Y. Ban, and J. W. Zhang. "Investigation on laser cladding Ni-base coating assisted by electromagnetic field." J. Opt Laser Technol., 114:81-88(2019), https://doi.org/10.1016/j.optlastec.2019.01.017


[4]      Ding, Lin, et al. "Effect of Mo and nano-Nd2O3 on the microstructure and wear resistance of laser cladding Ni-based alloy coatings." J. Appl. Phys. A, 122(4pt.1): 1-7(2016), https://doi.org/10.1007/s00339-016-9905-1


[5]      Xiang, Kang, et al. "Microstructural characteristics and properties of CoCrFeNiNbx high-entropy alloy coatings on pure titanium substrate by pulsed laser cladding." J. Appl. Surf. Sci, 517: 146214(2020), https://doi.org/10.1016/j.apsusc.2020.146214


[6]      A, Yan Liu, et al. "High temperature wear performance of laser cladding Co06 coating on high-speed train brake disc." J. Appl. Surf. Sci, 481: 761-6(2019), https://doi.org/10.1016/j.apsusc.2019.02.235


[7]      Li M., Han B., Song L., et al. "Enhanced surface layers by laser cladding and ion sulfurization processing towards improved wear-resistance and self-lubrication performances." J. Applied Surface Science 503(Feb.15): 144226.1-144226.11(2020), https://doi.org/10.1016/j.apsusc.2019.144226


[8]      Rong T, Gu D, Shi Q, et al. "Effects of tailored gradient interface on wear properties of WC /Inconel 718 composites using selective laser melting." J. Surf. Coat. Technol, 307: 418-27(2016), https://doi.org/10.1016/j.surfcoat.2016.09.011


[9]      Li Y, Hou C, Lu H, et al. "WC strengthened W-Cu nanocomposite powder synthesized by in-situ reactions." J. Int. J. Refract. Hard. Met., (79-), 79(2019), https://doi.org/10.1016/j.ijrmhm.2018.12.003


[10]   Gopinath, Muvvala, D. P. Karmakar, and A. K. Nath. "In-process detection of microstructural changes in laser cladding of in-situ Inconel 718/TiC metal matrix composite coating." J. Alloys Compd., 545-558(2018), https://doi.org/10.1016/j.jallcom.2017.12.364


[11]   Zhong, M., and W. Liu. "Laser surface cladding: The state of the art and challenges." J. P. I. MECH. ENG. C-J. MEC., 1989-1996 (vols 203-210), 224(5), 1041-1060(2010), https://doi.org/10.1243/09544062JMES1782


[12]   Yilbas, B. S., S. S. Akhtar, and C. Karatas. "Laser surface treatment of Inconel 718 alloy: Thermal stress analysis."J. Management World 48(7-8), 740-749(2010), https://doi.org/c 10.1016/j.optlaseng.2010.03.012


[13]   Zhu H, Li Y, Li B, et al. "Effects of Low-Temperature Tempering on Microstructure and Properties of the Laser-Cladded AISI 420 Martensitic Stainless Steel Coating." J. Coatings, 8.12(2018), https://doi.org/10.3390/coatings8120451


[14]   Hao F, Liao B, Li D, et al. "Effects of rare earth oxide on hardfacing metal microstructure of medium carbon steel and its refinement mechanism." J. Rare Earths, 029(006), P.609-613(2011), https://doi.org/10.1016/s1002-0721(10)60507-8


[15]   Golmakaniyoon, S., and R. Mahmudi. "Microstructure and creep behavior of the rare-earth doped Mg-6Zn-3Cu cast alloy." J. Mater. Sci. Eng. A, 528(3), 1668-1677(2011), https://doi.org/10.1016/j.msea.2010.10.095


[16]   Lu, X., Chen, F., Li, W., et al. "Effect of Ce addition on the microstructure and damping properties of Cu-Al-Mn shape memory alloys". J. Alloys Compd., "480"(2), "608-- 611"(2009), https://doi.org/10.1016/j.jallcom.2009.01.134


[17]   He, L., Xu, Z., Cao, X., Zhong, X., et al. "Adhesive strength of new thermal barrier coatings of rare earth zirconates. " J. Vacuum, 83(11), 1388-1392(2009), https://doi.org/10.1016/j.vacuum.2009.04.053


[18]   Zhang Z., Yang Q., Yu Z., et al. "Influence of Y2O3 addition on the microstructure of TiC reinforced Ti-based composite coating prepared by laser cladding." J. Mater. Charact., (189-), 189(2022), https://doi.org/10.1016/j.matchar.2022.111962


[19]   Chaofeng Wu, Mingxing Ma, Liu W, et al. "Laser cladding in-situ carbide particle reinforced Fe-based composite coatings with rare earth oxide addition." J. Rare Earths, 27(6), 997-1002(2009), https://doi.org/10.1016/S1002-0721(08)60377-4


[20]   Xing X., Han Z., Wang H., et al. "Electrochemical corrosion resistance of CeO2-Cr/Ti i coatings on 304 stainless steel via pack cementation." J. Rare Earths, 33(10), 1122-1128(2015), https://doi.org/10.1016/S1002-0721(14)60535-4


[21]   Wang K L , Zhang Q B , Sun M L, et al. "Rare earth elements modification of laser-clad nickel-based alloy coatings." J. Appl. Surf. Sci., 174(3-4), 191-200(2001), https://doi.org/10.1016/S0169-4332(01)00017-4


[22]   Yu D. Q., Zhao J., Wang L., "Improvement on the microstructure stability, mechanical and wetting properties of Sn–Ag–Cu lead-free solder with the addition of rare earth elements." J. Alloys Compd, 376(1-2), 170-175(2004), https://doi.org/10.1016/j.jallcom.2004.01.012


[23]   Li J, Luo X, Li G J, "Effect of Y2O3 on the sliding wear resistance of TiB/TiC-reinforced composite coatings fabricated by laser cladding." J. Wear, 310(1-2), 72-82(2014), https://doi.org/10.1016/j.wear.2013.12.019


[24]   Wang, D. S., Liang, E. J., Chao, M. J., Yuan, B., "Investigation on the microstructure and cracking susceptibility of laser-clad V2O5 /NiCrBSiC alloy coatings. " J. Surf. Coat. Technol., 202(8), 1371-1378(2008), https://doi.org/10.1016/j.surfcoat.2007.06.036


[25]   Zhu, R., Li, Z., Li, X., Sun, Q., "Microstructure and properties of the low-power-laser clad coatings on magnesium alloy with different amount of rare earth addition." J. Appl. Surf. Sci., 353(OCT.30), 405-413(2015), https://doi.org/10.1016/j.apsusc.2015.06.071


[26]   Prywer J. "Explanation of some peculiarities of crystal morphology deduced from the BFDH law." J. Cryst. Growth, 270(3-4), 699-710(2004), https://doi.org/10.1016/j.jcrysgro.2004.06.046

Published
2024/08/26
How to Cite
Zhang, C.- xiao, Sun, W.- chang, Liu, E.- yong, Liu, Y.- wan, Zhang, B., Zhou, M.- ran, & Xu, X. (2024). Effects of CeO2/Y2O3 rare earth oxides on microstructure and properties of in-situ synthesized WC-reinforced Ni-based cladding layer. Journal of Mining and Metallurgy, Section B: Metallurgy, 60(1), 139-152. Retrieved from https://aseestant.ceon.rs/index.php/jmm/article/view/47101
Section
Original Scientific Paper