Diffusion kinetics of boron in the X200CrMoV12 high-alloy steel

  • OMAR AZOUANI Commissariat à l’Energie Atomique. Centre de Recherche Nucléaire de Draria (CRND). BP 43, Draria, Alger, Algérie
  • Mourad KEDDAM USTHB, Faculté de Génie Mécanique et Génie des Procédés, Laboratoire de Technologie des Matériaux, Département SDM, B.P. 32 El-Alia, 1611 Bab-Ezzouar, Alger, Algérie
  • A. BRAHIMI Laboratoire de Traitement de Surface et Matériaux, Département de Génie Mécanique, Université Saad Dahlab, Route De Soumaa, B.P. 270 Blida, Algérie.
  • Abdelaziz SEHISSEH Commissariat à l’Energie Atomique. Centre de Recherche Nucléaire de Draria (CRND). BP 43, Draria, Alger, Algérie

Abstract


In this work, the kinetics of formation of the boride layers (FeB/Fe2B), formed on the X200CrMoV12 steel used for the cold-working, was investigated. The boriding treatment was carried out in the powder mixture consisting of 5%B4C, 5% NaBF4 and 90% SiC.

The boriding parameters are : 900, 950 and 1000°C with treatment times of 2, 4 and 6 h. The obtained borided layers (FeB/Fe2B) were characterized by the following experimental techniques: optical microscopy, scanning electron microscopy coupled to EDS analysis and XRD analysis. The kinetics of boron diffusion in the X200CrMoV12 steel was also studied. As a result, the time dependence of the borided layers thicknesses followed a growth parabolic law. The boron activation energy was estimated as 199.37 kJ mol-1 for the X200CrMoV12 steel. A full factorial design with 2 factors at 3 levels was employed to estimate the total boride layer thickness as a function of the boriding parameters (time and temperature) and a simple equation was proposed. Finally, an iso-thickness diagram was given as a tool to predict the total boride layers thicknesses in relation with the practical utilization of this kind of steel.

References

A.K. Sinha, J. Heat Treatment , 4 (1991), 437-447.

R. Chatterjee-Fisher, Boriding and diffusion metallizing. In: Sundarshan TS, editor. Surface modification technologies. NewYork: Marcel Dekker Inc.; 1989. p. 567 [chapter 8].

G. Çelebi, M.Ipeck, C. Bindal, A.H.Űcisik, Mater. Forum, 29 (2005) 456-460.

V.Jain, G.Sundararajan, Surf. Coat. Technol., 149 (2002) 21-26.

S. Şahin, J. Mater. Process Tech., 209 (2009) 1736-1741.

V.P. Glukhov, Boronizing steel, Sov. Powder Metall. Met. Ceram., 4 (76) (1969) 278–283.

C. Martini, G. Palombarini, G. Poli, D. Prandstraller, Wear 256 (2004) 608–613.

P. Goeuriot, R. Fillit, F. Thevenot, J. H. Driver and H. Bruyas, Mater. Sci. Eng., 55 (1982) 9 – 19.

V.I. Dybkov, W. Lengauer, K. Barmak, J. Alloy. Compd., 398 (2005) 113–122.

V. I. Dybkov, J. Mater. Sci., 42 (16) (2007) 6614-6627.

V. I. Dybkov, W. Lengauer, P. Gas, J. Mater. Sci. 41 (2006) 4948–4960.

C.M. Brakman, A.W.J. Gommers, E.J. Mittemeijer, J. Mater. Res., 4 (1989) 1354-1370

A. Kaouka, O. Allaoui, M. Keddam, Matériaux et Techniques, 101, 705 (2013).

Z. Nait Abdellah, M. Keddam, R. Chegroune, O. Azouani, O. Allaoui, A. Elias, Matériaux et Techniques, 100 (2012) 271-278.

I. Campos-Silva, M. Ortiz-Domínguez, O. Bravo-Bárcenas, M. A. Doñu-Ruiz, D.Bravo-Bárcenas, C. Tapia-Quintero , M.Y. Jiménez-Reyes, Surf. Coat. Technol., 205 (2010) 403-412.

I. Campos-Silva, M. Ortiz-Domínguez, C. Tapia-Quintero, G. Rodriguez-Castro, M.Y. Jimenez-Reyes, E. Chavez-Gutierrez, J. Mater. Eng. Perform., 21 (2012) 1714-1723.

JCPDS- International Centre for Diffraction Data, PCPDF WIN, Version 202 (1999).

N. Ucar, O. B. Aytar, A. Calik, Mater.Technol., 46 (2012) 621–625

X. Tian, Y. L. Yang, S. J. Sun, J. An, Y. Lu, Z. G. Wang, J. Mater. Eng. Perform., 18 (2009) 162

] L. Xu, X. Wu, H. Wang, J. Mater. Sci. Technol., 23 (2007) 525

S. Taktak, Mater. Sci., 41 (2006) 7590–7596.

Z. Nait Abdellah, M. Keddam, A. Elias, Int. J. Mater. Res., 104 (2013) 260-265.

K. Genel, Vacuum 80 (2006) 451

I. Uslu, H. Comert, M.Ipek, F.G. Celebi, O. Ozdemir, C. Bindal, Mater. Design, 28 (2007) 1819

M. Ipek, G. Celebi Efe, I. Ozbek, S. Zeytin, and C. Bindal, J. Mater. Eng. Perform. 21 (2012) 733-738

J.H. Yoon, Y.K. Jee, S.Y, Lee, Surf. Coat. Technol., 112 (1999) 71–75.

J. Goupy, Plans d’expériences pour surfaces de réponses, Edition Dunod, (2001).

Published
2015/02/24
How to Cite
AZOUANI, O., KEDDAM, M., BRAHIMI, A., & SEHISSEH, A. (2015). Diffusion kinetics of boron in the X200CrMoV12 high-alloy steel. Journal of Mining and Metallurgy, Section B: Metallurgy, 51(1), 49. Retrieved from https://aseestant.ceon.rs/index.php/jmm/article/view/5866
Section
Original Scientific Paper