Phase and roughness analysis of nanocrystalline coatings based on 310S steel with aluminum additions
Abstract
Aluminum alloying is commonly used to improve high-temperature oxidation resistance. In this study, Al was incorporated into nanocrystalline coatings produced by magnetron sputtering of 310S chromium–nickel steel. The effect of this addition on the phase composition and morphology of the coatings, which influence the formation of protective oxide layers under high-temperature conditions, was investigated. The coatings were analyzed using scanning electron microscopy (SEM) and atomic force microscopy (AFM), with emphasis on surface roughness, as well as X-ray diffractometry (XRD) to determine crystallite size and phase composition. The results showed that the addition of aluminum affects phase stability in the coatings. At Al contents of 1–2 at.%, there is a twofold reduction in the fraction of the fcc phase in the coating (and its disappearance at 5 at.%), along with a similar decrease in surface roughness. At the same time, crystallite size increases while the nanocrystalline structure is retained, creating favorable conditions for the formation of dense Al₂O₃ oxide layers on the coatings.
References
J. Musil, J. Vlček, A perspective of magnetron sputtering in surface engineering, Surface and Coatings Technology, 112 (1999) 162–169. https://doi.org/10.1016/S0257-8972(98)00748-8
M.W. Posadowski, Nowoczesne techniki rozpylania magnetronowego, Elektronika, 4 (2006) 40–43.
K. Mars, M. Sałęga-Starzecki, K.M. Zawadzka, E. Godlewska, Influence of sputtering power on the properties of magnetron sputtered tin selenide films, Materials, 17 (13) (2024) 3132. https://doi.org/10.3390/ma17133132
M. Betiuk, PVD and PAPVD technologies in practice, Surface Engineering, 2 (2005) 3–13.
W.M. Posadowski, A. Wiatrowski, J. Dora, Z.J. Radzimski, Magnetron sputtering process control by medium-frequency power supply parameter, Thin Solid Films, 516 (2008) 4478–4482. https://doi.org/10.1016/j.tsf.2007.05.077
B. Wendler, S. Bin, Oxidation resistant FeAlCrSi and SiCx coatings on ferritic AISI 430 stainless steel, Inżynieria Materiałowa – Materials Engineering, 3–4 (2007) 804–809.
Y.-C. Chang, Y.-C. Chen, C.-C. Cheng, Fabrication of AlGaN high frequency bulk acoustic resonator by reactive RF magnetron co-sputtering system, Materials, 14 (23) (2021) 7377. https://doi.org/10.3390/ma14237377
B. Kucharska, PVD coatings made of chrome-nickel steel modified with Al, Ir, Re and Ru additives, Czestochowa University of Technology, Częstochowa, 2011.
B. Kucharska, B. Wendler, M. Danielewski, Characteristics of AISI310S steel-based coatings deposited by magnetron sputtering on AISI 304 steel substrate, Inżynieria Materiałowa – Materials Engineering, 3 (2006) 463–466.
T. Zlamal, I. Mrkvica, T. Szotkowski, S. Malotova, The influence of surface treatment of PVD coating on its quality and wear resistant, Coatings, 9 (7) (2019) 439. https://doi.org/10.3390/coatings9070439
B.G. Segda, M. Jacquet, J.P. Besse, Elaboration, characterization and dielectric properties study of amorphous alumina thin films deposited by r.f. magnetron sputtering, Vacuum, 62 (2001) 27–38. https://doi.org/10.1016/S0042-207X(01)00114-2
M.-J. Liu, M. Zhang, X.-F. Zhang, G.-R. Li, Q. Zhang, C.-X. Li, C.-J. Li, G.-J. Yang, Transport and deposition behaviors of vapor coating materials in plasma sprayphysical vapor deposition, Applied Surface Science, 486 (2019) 80–92. https://doi.org/10.1016/j.apsusc.2019.04.224
J.A. Thornton, High rate thick film growth, Annual Review of Materials Science, 7 (1977) 239–260. https://doi.org/10.1146/annurev.ms.07.080177.001323
E. Locks, Q. He, J.M. De Paiva, M. Guimaraes, A.F. Arif, S.C. Veldhuis, J.R. Kish, Investigating the impact of physical vapour deposition (PVD)-coated cutting tools on stress corrosion cracking susceptibility in turning super duplex stainless steel, Coatings, 14 (3) (2024) 290. https://doi.org/10.3390/coatings14030290
T. Zlamal, I. Mrkvica, T. Szotkowski, S. Malotova, The influence of surface treatment of PVD coating on its quality and wear resistant, Coatings, 9 (7) (2019) 439. https://doi.org/10.3390/coatings9070439
J. Osés, G.G. Fuentes, J.F. Palacio, J. Esparza, J.A. García, R. Rodríguez, Antibacterial functionalization of PVD coatings on ceramics, Coatings, 8 (5) (2018) 197. https://doi.org/10.3390/coatings8050197
B. Kucharska, Measurement of Fe-Cr-Ni coatings density in XRD analysis, Inżynieria Materiałowa – Materials Engineering, 28 (3–4) (2007) 419–421.
M. Danielewski, B. Wierzba, B. Kucharska, New possibility to extend Wagner method for oxidation process modelling, Inżynieria Materiałowa – Materials Engineering, 6 (166) (2008) 830–834.
W. Gao, Z. Li, Nano-structured alloy and composite coatings for high temperature application, Materials Research, 7 (1) (2004) 175–182. https://doi.org/10.1590/S1516-14392004000100023
Z. Liu, W. Gao, M. Li, Cyclic oxidation of sputterdeposited nanocrystalline Fe-Cr-Ni-Al alloy coatings, Oxidation of Metals, 51 (5–6) (1999) 51–63. https://doi.org/10.1023/A%3A1018835126181
B. Wendler, S. Bin, Oxidation resistant FeAlCrSi and SiCx coatings on ferritic AISI 430 stainless steel, Inżynieria Materiałowa – Materials Engineering, 3–4 (2007) 804–809.
M. Mróz, S. Olszewska, P. Rąb, Evaluation of the possibility to improve the scratch resistance of the AZ91 alloy by applying a coating, Archives of Foundry Engineering, 4 (2023) 157–162. https://doi.org/10.24425/afe.2023.146690
H. Kun, H. Gong, K. Zeng, Z. Li, W. Gao, Oxidation behaviour of stainless steel-A1 coatings produced by co-sputtering and reactive sputtering, Materials Letters, 46 (2000) 53–59. https://doi.org/10.1016/S0167- 577X(00)00142-7
B. Kucharska, Diffractometric examination of the structure of heat-resisting steel-based coatings in different measurement geometries, Central European Journal of Physics, 9 (5) (2011) 1294–1300. https://doi.org/10.2478/s11534-011-0027-2
X. Zhang, A. Misra, R.K. Schulzer, C.J. Wetteland, H. Wang, M. Nastasi, Critical factors that determined face-centered to body-centered cubic phase transformation in sputter-deposited austenitic stainless steel films, Vacuum, 66 (2002) 257–261. https://doi.org/10.1557/JMR.2004.0215
P. Dasgupta, On use of pseudo-Voigt profiles in diffraction line broadening analysis, Fizika A, 9 (2) (2000) 61–66.
Z. Liu, W. Gao, Y.He, Oxidation behaviour of nanocrystalline Fe–Ni–Cr–Al alloy coatings, Materials Science and Technology, 15 (12) (1999) 1447-1450. https://doi.org/ 10.1179/026708399101505446
Y. Karanth, S. Sharma, K. Darling, H. El Kadiri, K. Solanki, Oxidation Behavior of Nanocrystalline Alloys, Materials. 17 (23) 5842 (2024). https://doi.org/10.3390/ma17235842
N. Birbilis, J. Zhang, R Gupt, Oxidation Resistance of Nanocrystalline Alloys, in Corrosion Resistance. InTech. (2012). https://doi.org/10.5772/34928
W.J. Nowak, D. Serafin, B. Wierzba, Effect of surface mechanical treatment on the oxidation behavior of FeAl-model alloy, Journal of Materials Science 54, 9185–9196 (2019). https://doi.org/10.1007/s10853-019-03509-5
W.J.Nowak, B. Wierzba, Effect of Surface Treatment on High-Temperature Oxidation Behavior of IN 713C. Journal of Materials Engineering and Performance 27, 5280–5290 (2018). https://doi.org/10.1007/s11665-018-3621-2
Z. Liu, G. Wang, W. Gao, Properties of 310S stainless steel coatings produced by unbalanced magnetron sputter deposition, Materials Characterization, 54 (2005) 466–472. https://doi.org/10.1016/j.matchar.2005.02.001
J. Wang, M. Chen, L. Yang, W. Sun, A. Zhu, F. Wang, Nanocrystalline coatings on superalloys against high temperature oxidation: A review, Corrosion Communications, 2 (2021) 55–62. https://doi.org/10.1016/j.corcom.2021.09.002
R. Kumar, R.K. Singh Raman, S.R. Bakshi, V.S. Raja, S. Parida, Exploring the Influence of Nanocrystalline Structure and Aluminum Content on High-Temperature Oxidation Behavior of Fe-Cr-Al Alloys. Materials, 17 1700 (2024). https://doi.org/10.3390/ma17071700
S. Nasiri, M. Rabiei, A. Palevicius, G. Janusas, A. Vilkauskas, V. Nutalapati, A. Monshi, Modified Scherrer equation to calculate crystal size by XRD with high accuracy, examples Fe₂O₃, TiO₂ and V₂O₅, Nano Trends, 3 (2023) 100015. https://doi.org/ 10.1016/j.nwnano.2023.100015
S. Inoue, T. Saeki, H. Uchida, K. Koterazawa, M. Iwasa, Effect of ion flux on the properties of dc magnetron-sputtered stainless steel films, Vacuum, 66 (2002) 257–261. https://doi.org/10.1016/S0042-207X(02)00151-3
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