Activity of bismuth in liquid Ag-Bi-Ni alloys determined by equilibrium saturation method

  • Przemyslaw Fima Institute of Metallurgy and Materials Science, Polish Academy of Sciences
  • Jolanta Romanowska Rzeszow University of Technology

Abstract


Activity coefficients of Bi in liquid Ag-Bi-Ni alloys were experimentally determined by means of the equilibrium saturation method at 1173 and 1273 K. The measurements were carried out for alloy compositions along three sections of fixed Ag to Ni mole fraction ratio equal to 4, 3/2, and 2/3. The excess Gibbs free energy of Bi was calculated basing on the experimental activity coefficient data. The experimental activity data were compared to the values calculated for two sets of  assessed thermodynamic data.

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Published
2015/02/24
How to Cite
Fima, P., & Romanowska, J. (2015). Activity of bismuth in liquid Ag-Bi-Ni alloys determined by equilibrium saturation method. Journal of Mining and Metallurgy, Section B: Metallurgy, 51(1), 105. Retrieved from https://aseestant.ceon.rs/index.php/jmm/article/view/6462
Section
Original Scientific Paper