Kinetic Investigation of AISI 304 Stainless Steel Boronized in Indirect Heated Fluidized Bed Furnace
Abstract
In this study, kinetic examinations on boronized AISI 304 Stainless Steel samples were described. Samples were boronized in indirect heated fluidized bed furnace consists of Ekabor 1™ boronizing agent at 1123, 1223 and 1323 K for 1,2 and 4 hours. Morphologically and typically examinations of borides formed on the surface of steel samples were studied by optical microscope, scanning electron microscope (SEM) and X-Ray diffraction (XRD).Boride layer thickness formed on the steel X5CrNi 18-10 ranges from 12 to 176µm. The hardness of the boride layer formed on the steel X5CrNi 18-10 varied between 1709 and 2119 Hv0,1. Layer growth kinetics were analyzed by measuring the extent of penetration of FeB and Fe2B sublayers as a function of boronizing time and temperature. The kinetics of the reaction has been determined with K=Ko exp (-Q/RT) equation. Activation energy (Q) of boronized steel X5CrNi 18-10 was determined as 244 kj/mol.
References
R. Beatty. The Element Boron, Marshall Cavendish Corp., 99 White Plains Road, Tarrytown, New York 10591,Printed in China, 2005, p.4. ISBN: 13-978-0-7614-1921-1
R.Adair, Boron (Understanding the Elements of the Periodic Table), Rosen Publishing Group, 29 East 21st St. New York, NY 10010, 2007,p.19. ISBN-10: 1404210040
DIN 17014-3: 1976-05 “Heat Treatment of Ferrous Materials; Notation to Indicate Heat Treatment Processes”, English Version.
P.Topuz, E.Yılmaz, E.Gündoğdu, Materials Testing,56(2), (2014), p.104-110. doi: 10.3139/120.110531
R.W. Reynoldson. Heat Treatment in Fluidized Bed Furnaces, The Materials Information Society, Materials Park, OH, ASM International, 1993.
İ.Özbek, C. Bindal, Surface & Coatings Technology, 154, 2002, p.14-20, DOI: 10.1016/S0257-8972(01)01409-8
B.S Mann, Wear, 208 (1997), p. 125–131. DOI:10.1016/S0043-1648(96)07374-7
.R.X. Yan, X.M. Zhang, J.W. Xu, Z.G. Wu,Q.M. Song, Materials Chemistry and Physics,71(1) 2001, p. 107–110. DOI: 10.1016/S0254-0584(01)00270-X
AK. Sinha, Boriding (Boronizing), “ASM Handbook, Vol 4: Heat Treating”. Materials Park, OH: ASM International, (1991) p.978-998
O.Ozdemir, M.A.Omar, M.Usta, S. Zeytin, C.Bindal, A.H. Ucisik, Vacuum, 83, 2008, p.175-179. DOI: 10.1016/j.vacuum.2008.03.026
A. Bouayad, Ch. Gerometta, A. Belkebir, A. Ambari, Materials Science and Engineering, 363(1-2) 2003, p. 53-61. DOI: 10.1016/S0921-5093(03)00469-6
S.Taktak, J.Mater.Science, 41, 2006, p.7590-7596.
Y.Kayalı, The Physics of Metals and Metallography, 114(12), 2013, p.1061-1068. Doi: 10.1134/S0031918X1322002X
J.H.Yoon, Y.K.Jee, S.Y.Lee, Surface and Coating Technology, 112, 1999, p.71-75. Doi: 10.1016/S0257-8972(98)00743-9
Authors retain copyright of the published papers and grant to the publisher the non-exclusive right to publish the article, to be cited as its original publisher in case of reuse, and to distribute it in all forms and media.
The Author(s) warrant that their manuscript is their original work that has not been published before; that it is not under consideration for publication elsewhere; and that its publication has been approved by all co-authors, if any, as well as tacitly or explicitly by the responsible authorities at the institution where the work was carried out. The Author(s) affirm that the article contains no unfounded or unlawful statements and does not violate the rights of others. The author(s) also affirm that they hold no conflict of interest that may affect the integrity of the Manuscript and the validity of the findings presented in it. The Corresponding author, as the signing author, warrants that he/she has full power to make this grant on behalf of the Author(s). Any software contained in the Supplemental Materials is free from viruses, contaminants or worms.The published articles will be distributed under the Creative Commons Attribution ShareAlike 4.0 International license (CC BY-SA).
Authors are permitted to deposit publisher's version (PDF) of their work in an institutional repository, subject-based repository, author's personal website (including social networking sites, such as ResearchGate, Academia.edu, etc.), and/or departmental website at any time after publication.
Upon receiving the proofs, the Author(s) agree to promptly check the proofs carefully, correct any typographical errors, and authorize the publication of the corrected proofs.
The Corresponding author agrees to inform his/her co-authors, of any of the above terms.