Properties and structure of tungstencarbide – cobalt coatings deposited by the APS - plasma spray process

  • Mihailo Rade Mrdak IMTEL komunikacije a.d.
Keywords: property, powders, plasmas, gas flow, gas, deposits, Cobalt, Coatings,

Abstract


The aim of this study was to optimize the parameters of the plasma spray and to deposit WC17Co layers with optimal structural - mechanical characteristics. The powder was deposited by the plasma spraying process at the atmospheric pressure (APS). When choosing the parameters, the flow of the He plasma gas was taken as the basic parameter. In relation to other gases, helium does not react with the powder,it produces a denser plasma with a lower heat content and it incorporates less ambient air into the plasma jet which reduces decarburization of the powder. The study shows three groups of samples obtained with three plasma gas flows of 12, 22 and 32 l/min He. The coating with the best properties was deposited on the shaft sleeve of the main rotor of the Gazelle H42 helicopter, in order to reduce the influence of vibrations and bearings on sleeve wear up to 500°C. The estimates of the  WC17Co layers of the  coating were made on the basis of their structural - mechanical properties. The surface morphology of the WC17Co powder particles was examined on the SEM. The mechanical properties of the deposited coatings were tested in accordance with the ‘TURBOMECA’standard. The estimate of the mechanical properties of layers was done by examining microhardness with the method HV0.3 and bond strength with tensile testing. Metallographic assessment of the pore proportion in the layers of the WC17Co coating (image analysis) was performed with the technique of light microscopy in accordance with the ‘Pratt & Whitney’ standard. Studies have shown that the rate of the plasma gas flow significantly affects the mechanical properties and the structure of coatings.

 

Author Biography

Mihailo Rade Mrdak, IMTEL komunikacije a.d.
Doctor of Technical Sciences

References

ASM Handbook, 1992, Volume 3, Alloy Phase Diagrams, ASM International, Printed in the United States of America, Metals Park.

Brossard, S., Munroe, P.R., Tran, A.T.T., Hyland, M.M., 2010, Study of the effects of surface chemistry on splat formation for plasma sprayed NiCr onto stainless steel substrates, Surface and Coatings Technology, 204, 9-10, pp.1599-1607.

de Villiers Lovelock, H.L., 1998, Powder/processing/structure relationships in WC-Co thermal spray coatings: a review of the published literature, Journal of Thermal Spray Technology, 7(3), pp.357–373.

Dorfman, M.R., 2002, Thermal spray basics, Advanced Materials & Processes, 160(7), pp.47-50.

Li, C.-J., Ohmori, A. and Harada, Y., 1996, Effect of WC-Co powder structure on the structure of thermally sprayed WC-Co coatings, J. Mater. Sci., 31, pp.785-794.

Material Product Data Sheet, 2011, Metco 73F-NS-1 Tungsten Carbide-17% Cobalt Powder, DSMTS – 0030.2, Sulzer Metco.

Mrdak, M., Kakaš, D., Pović, Đ., 2004, Karakterizacija plazma-sprej prevlaka Cr3C225NiCr i WC17Co otpornih na habanje i koroziju, Istraživanje i Razvoj Mašinskih Elemenata i Sistema, IRMES ’04, Kragujevac, pp.407-421.

Mrdak, М., 2010, Karakterizacija WCCo/NiCrBSi prevlake otporne na habanje, Vojnotehnički glasnik 2/10, pp.43 - 52.

Mrdak, M., Kakaš, D., Pović, Đ., 2003, Ispitivanje strukturnih i mehaničkih osobina prevlaka sa povišenom otpornošću na habanje, 8th Internacionalna konferencija o tribologiji, Beograd, Srbija, pp.125 -128.

Roumilhac, Ph., Coudert, J.F., Leger, J.M., Fauchais, P., 1988, Characterization of a D.C.Spraying Plasma Torch using Optical and Thermal Diagnostics, Proceedings of the 1st Plasma-Technik Symposium, Switzerland, Lucerne, 1, pp.105-119.

Roumilhac, Ph., Fauchais, P., 1988, Optical and Thermal Diagnostics Regarding the Working Conditions of a Plasma Spray Mini Torch, Proceedings of the 1st Plasma-Technik Symposium, Switzerland, Lucerne, 1, pp.121-126.

Saha, G.C., Mateen, A., Khan, T.I., 2010, Tribological Studies of Conventional Microcrystalline and Engineered Near-Nanocrystalline WC-17Co HVOF Coatings, NSTI – Nanotech 2010, ISBN 978-1-4398-3401-5 (1), pp.592-595.

Stewart, D.A., Shipway, P.H., and McCartney, D.G., 2000, Microstructural evolution in thermally sprayed WC-Co coatings: comparison between nanocomposite and conventional starting powders, Acta Materialia, 48(7), pp. 1593 – 1604.

Turbojet engine-standard practices manual TURBOMECA.

Turbojet Engine – Standard Practices Manual (PN 582005), 2002, Pratt & Whitney, East Hartford, USA.

Valiev, R., 2002, Nature, 419, pp.887-889.

Vencl, A., Mrdak, M., Cvijović, I., 2006, Microstructures and tribological properties of ferrous coatings deposited by APS (Atmospheric Plasma Spraying) on Al-alloy substrate, FME Transactions, 34(3), pp.151-157.

Published
2013/10/09
Section
Original Scientific Papers